Diacetone-D-Glucose

Basic information

  • Product Name:Diacetone-D-Glucose
  • CasNo.:582-52-5
  • MF:C12H20O6
  • MW:260.287

Physical and Chemical Properties

  • Boiling Point:110-111 °C(lit.)
  • Packing:
  • Throughput:
Inquiry

Product Details

CasNo: 582-52-5

MF: C12H20O6

Appearance: white to light yellow crystal powder

Offer Chemical Raw Material Diacetone-D-Glucose 582-52-5 In Stock

Synonyms: Diacetone-D-glucose;1,2:5,6-Diisopropylidene-D-glucose;D-Glucose diacetonide; Diacetone glucose.

Molecular Formula: C12H20O6

Molecular weight: 260.28

CAS No.: 582-52-5

EC No.: 209-486-0

RTECS: LZ49580000

Quality Standard:

Item

Specification

Appearance

White crystalline power

Melting Point, ℃

107-113

Assay,%

≥98

Specific rotation, (C=2, H2O )

-17~ -19

Heavy Metals,ppm

≤ 10

Loss on drying,%

≤1.0

Residue on ignition,%

≤0.1

TLC

Single spot

Properties: It's white crystalline powder.It's not flammability.It's innocuity.

Diacetone-D-glucose(Cas 582-52-5) Usage

 It is mainly used in biochemical reaction and used as medicine intermediate. For example cephalosporin and penicilline. It is used in synthesize for below products: L-gulose; 1,2:5,6-Di-O-isopropylidene-a-D-gulofuranose; Alllose; 1,2:5,6-Double-O-Isopropylidene-3-C-(1-Methoxycarbonyl)Ethide-α-D-Furanose); 1,2:5,6-Di-O-isopropylidene-a-D-ribo-hexofuranose-3-ulose;6-deoxy idose; L-acovenose;3-O-Methyl-1,2:5,6-di-O-isopropylidene-a-D- glucofuranose ;3-O-acryloyl-1,2:5,6-di-O-isopropylidene-a-D- glucofuranose;3-O-Methacryloyl-1,2:5,6-di-O-isopropylidene-a-D- glucofuranose; 3-O-Allyl-1,2:5,6-di-O-isopropylidene-a-D- glucofuranose; 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-a-D-glucofuranose; 3-O-Acetyl-1,2:5,6-di-O-isopropylidene-a-D-glucofuranose; 3-O-[2-Dimethylaminoethyl]-1,2:5,6-bis-O-1-methylethylidene-a-D-glucofuranose; 1,2:5,6-Di-O-isopropylidene-3-O-methylsulfonyl-alpha-D-glucofuranose; 3-Deoxy-1,2:5,6-di-O-isopropylidene-D-glucose

Storage: Store in a tightly closed container. Store in a cool and dry area.

Package: 10kgs/drum or as required by the customer.

582-52-5 Relevant articles

Direct Access to 2,3,4,6-Tetrasubstituted Tetrahydro-2H-pyrans via Tandem SN2′-Prins Cyclization

Scoccia, Jimena,Pérez, Sixto J.,Sinka, Victoria,Cruz, Daniel A.,López-Soria, Juan M.,Fernández, Israel,Martín, Víctor S.,Miranda, Pedro O.,Padrón, Juan I.

, p. 4834 - 4837 (2017)

A new, direct, and diastereoselective sy...

Toward the construction of dermatan sulfate (DS) partial disaccharide library: Efficient synthesis of building blocks, common intermediate, and ligand conjugate of type-B DS disaccharide

Kakitsubata, Yuhei,Aramaki, Rikiya,Nishioka, Kyosuke,Wakao, Masahiro,Suda, Yasuo

, p. 1154 - 1157 (2016)

Dermatan sulfate (DS) is composed of a r...

Properties, stability, assay, and preliminary pharmacokinetics of the immunomodulatory 1,2-O-isopropylidene-3-O-3'(N',N'-dimethylamino-n-propyl)-D-glucofuranose hydrochloride

Garrett,Van Peer,Mahrous,Schuermann

, p. 387 - 395 (1982)

1,2-O-Isopropylidene-3-O-3(N',N'-dimethy...

METHODS FOR MAKING DARUNAVIR P2-LIGAND PRECURSORS

-

Paragraph 0008; 0022; 0033, (2022/02/28)

A method for making an optically active ...

Visible-Light-Mediated Oxidative Debenzylation Enables the Use of Benzyl Ethers as Temporary Protecting Groups

Cavedon, Cristian,Sletten, Eric T.,Madani, Amiera,Niemeyer, Olaf,Seeberger, Peter H.,Pieber, Bartholom?us

supporting information, p. 514 - 518 (2021/01/26)

The cleavage of benzyl ethers by catalyt...

Exploring the Biochemical Foundations of a Successful GLUT1-Targeting Strategy to BNCT: Chemical Synthesis and in Vitro Evaluation of the Entire Positional Isomer Library of ortho-Carboranylmethyl-Bearing Glucoconjugates

Matovi?, Jelena,J?rvinen, Juulia,Sokka, Iris K.,Imlimthan, Surachet,Raitanen, Jan-Erik,Montaser, Ahmed,Maaheimo, Hannu,Huttunen, Kristiina M.,Per?niemi, Sirpa,Airaksinen, Anu J.,Sarparanta, Mirkka,Johansson, Mikael P.,Rautio, Jarkko,Ekholm, Filip S.

, p. 285 - 304 (2020/12/21)

Boron neutron capture therapy (BNCT) is ...

Method for synthesizing release type xylose ester perfume for tobacco perfuming

-

Paragraph 0026-0028; 0041-0043; 0056-0058, (2021/10/27)

A synthesis method of a release type xyl...

582-52-5 Process route

3-O-(2-azidomethyl)phenylacetyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
428500-97-4

3-O-(2-azidomethyl)phenylacetyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

1,4-dihydro-3(2H)-isoquinolinone
24331-94-0

1,4-dihydro-3(2H)-isoquinolinone

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
Conditions Yield
With hydrogen; Lindlar's catalyst; In methanol; at 20 ℃; for 3h;
100%
(3aR,5R,6S,6aR)-6-(3,5-Dimethoxy-benzyloxy)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

(3aR,5R,6S,6aR)-6-(3,5-Dimethoxy-benzyloxy)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

3,5-dimethoxybenzaldehdye
7311-34-4

3,5-dimethoxybenzaldehdye

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
Conditions Yield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; for 2.5h; Ambient temperature;
86%

582-52-5 Upstream products

  • 50-99-7
    50-99-7

    D-glucose

  • 67-64-1
    67-64-1

    acetone

  • 70542-35-7
    70542-35-7

    (3aR,5R,6R,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-nitrooxy-tetrahydro-furo[2,3-d][1,3]dioxole

  • 31818-51-6
    31818-51-6

    Diethyl-thiocarbamic acid O-[(3aR,5R,6S,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl] ester

582-52-5 Downstream products

  • 109984-82-9
    109984-82-9

    O3-butyryl-O1,O2;O5,O6-diisopropylidene-α-D-glucofuranose

  • 40437-18-1
    40437-18-1

    O3-diphenoxyphosphino-O1,O2;O5,O6-diisopropylidene-α-D-glucofuranose

  • 63096-92-4
    63096-92-4

    1,2:5,6-di-O-isopropylidene-3-O-trityl-α-D-glucofuranose

  • 165589-85-5
    165589-85-5

    1,2:5,6-di-O-isopropylidene-3-(N-phenylthioxocarbamoyl)-α-D-glucofuranose