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Diacetone-D-Galactose

Basic information

  • Product Name:Diacetone-D-Galactose
  • CasNo.:4064-06-6
  • MF:C12H20O6
  • MW:260.287

Physical and Chemical Properties

  • Purity:99%
  • Boiling Point:120-122 °C
  • Packing:25kg/drum or as required by customer.
  • Throughput:
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Product Details

CasNo： 4064-06-6

MF： C12H20O6

Appearance： Thick yellow oil

Packing： 25kg/drum or as required by customer.

Purity： 99%

99% Purity Commercial production Diacetone-D-Galactose 4064-06-6 with Cheapest Price

Synonym: 1,2:3,4-Di-O-isopropylidene-α-D-galactopyranose; 1,2:3,4-Di-O-isopropylidene-D-galactopyranose;1,2:3,4-Di-O-isopropylidene-α-D-galactose; 1,2:3,4-Di-O-isopropylidene-D-galactose;1,2:3,4-O-Diisopropylidene-α-D-galactopyranose; 1,2:3,4-bis-O-(1-methylethylidene)-D-galactopyranos; Diisopropylidenegalactose.

Molecular Formula: C12H20O6

Molecular weight: 260.28

CAS No.: 4064-06-6

EC No.: 223-771-7

Molecular structure:

Quality Standard:

Item

Specification

Appearance

Colorless to yellow viscous liquid

Assay (GC), %

≥95.0

Specific rotation , （C=3，CHCl3）

 -55.0～-61.0

Loss on drying, %

≤1.0

Residue on ignition, %

≤0.1

Properties: Colorless to yellow viscous liquid. Dissolve in hot water, acetone, ethanol, tetrahydrofuran etc.

1,2:3,4-Di-O-isopropylidene-D-galactopyranose(Cas 4064-06-6) Usage

 As a derivative of natural sugar ,it has been widely used in medicine ,materials, dyes, spices and so on.

Can be used as pharmaceutical intermediates for the synthesis of carbohydrate drugs which are usually low toxic and side effect and high biological activity. used for the treatment of skin diseases and used in cosmetic provided with anti-wrinkle,anti-aging,smooth etc,and dermatopathya treatment. Modification of hydrocodone, opium and other analgesic drugs, can enhance the efficacy or reduce addiction, to reduce the control of drug abuse objective.

It also be used for the synthesis of biological probes which have wide application prospect in pharmaceutical and medical aspects. Such as modification of porphyrin and the formation of the carbohydrate porphyrin compounds, has excellent photophysical behavior and biocompatibility, which can be used for near infrared probe and a photosensitive drug, diagnosis and treatment of tumors.

Diacetone galactose can also be used in the synthesis of functional polymer materials. Also can be used for the synthesis of a new environmentally friendly dye, Used in synthesis of perfluoroalkylated derivatives of D-galactopyranose. Used in synthesis terpenoid-O-glycosides, which are food spice and Perfume.

Storage: Store in a tightly closed container. Store in a cool and dry area.

Package: 25kg/drum or as required by customer.

4064-06-6 Relevant articles

Reductive Cleavage of Sulfonates. Deprotection of Carbohydrate Tosylates by Photoinduced Electron Transfer

Masnovi, John,Koholic, Dolores J.,Berki, Robert J.,Binkley, Roger W.

, p. 2851 - 2853 (1987)

-

-

Lloyd,Roberts

, p. 6910,6912 (1965)

-

Rapid synthesis of 1-deoxygalactonojirimycin using a carbamate annulation

Timmer, Mattie S.M.,Dangerfield, Emma M.,Cheng, Janice M.H.,Gulab, Shivali A.,Stocker, Bridget L.

, p. 4803 - 4805 (2011)

A remarkably efficient synthesis of the ...

Covalent Lectin Inhibition and Application in Bacterial Biofilm Imaging

Wagner, Stefanie,Hauck, Dirk,Hoffmann, Michael,Sommer, Roman,Joachim, Ines,Müller, Rolf,Imberty, Anne,Varrot, Annabelle,Titz, Alexander

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Biofilm formation by pathogenic bacteria...

Ready preparation of sugar acetals under ultrasonic irradiation

Einhorn, Cathy,Luche, Jean-Louis

, p. 258 - 261 (1986)

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Hypervalent iodine system for debenzylation of sugars

Telvekar, Vikas N.

, p. 2647 - 2650 (2007)

A simple and mild system using 4,4′-bis-...

Thermoresponsive copolymers with pendant d-galactosyl 1,2,3-triazole groups: Synthesis, characterization and thermal behavior

Dhumure, Archana B.,Patil, Ajay B.,Kulkarni, Anuja S.,Voevodina, Irina,Scandola, Mariastella,Shinde, Vaishali S.

, p. 8179 - 8187 (2015)

A galactose containing glycomonomer has ...

Synthesis of new five membered nitrogen containing heterocycles bearing D-galactose side chains

Klier,Alves,Prado,De Souza Filho,D'Accorso

, p. 4361 - 4374 (2000)

The synthesis of 5-[6'-deoxy-(1',2':3',4...

-

Horton et al.

, p. 56,62 (1968)

-

Synthesis of amphiphilic galactopyranosyl diamines and amino alcohols as antitubercular agents

de Almeida, Mauro Vieira,Le Hyaric, Mireille,Amarante, Giovanni Wilson,Silva Lourenco, Maria Cristina,Lima Brandao, Marcelo Luiz

, p. 1076 - 1083 (2007)

Mono- and diacylated derivatives of gala...

Synthesis, spectroscopic studies, and x-ray crystallographic analysis of the organotin carbohydrate: 1,2:3,4-di-O-isopropylidene-6-O-triphenylstannylmethyl-α-D-galactopyranose

Cox, Philip J.,Melvin, Olga A.,Garden, Simon J.,Wardell, James L.

, p. 469 - 476 (1995)

The title organotin carbohydrate, C31H36...

Helical Self-Assembly of Optically Active Glycoconjugated Phthalocyanine J-Aggregates

B?chle, Felix,Maichle-M?ssmer, C?cilia,Ziegler, Thomas

, p. 1081 - 1093 (2019)

Four galactoconjugated zinc(II) phthaloc...

-

Dmitriev et al.

, p. 25,26-34 (1976)

-

Conformation of the Galactose Ring Adopted in Solution and in Crystalline Form as Determined by Experimental and DFT 1H NMR and Single-Crystal X-ray Analysis

Roslund, Mattias U.,Klika, Karel D.,Lehtilae, Reko L.,Taehtinen, Petri,Sillanpaeae, Reijo,Leino, Reko

, p. 18 - 25 (2004)

The solution-state conformations of vari...

Me3SI-promoted chemoselective deacetylation: a general and mild protocol

Gurawa, Aakanksha,Kashyap, Sudhir,Kumar, Manoj

, p. 19310 - 19315 (2021/06/03)

A Me3SI-mediated simple and efficient pr...

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This study presents the novel concept of...

Stereoselective Phenylselenoglycosylation of Glycals Bearing a Fused Carbonate Moiety toward the Synthesis of 2-Deoxy-β-galactosides and β-Mannosides

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supporting information, (2020/04/09)

A phenylselenoglycosylation reaction of ...

General Strategy for Integrated Bioorthogonal Prodrugs: Pt(II)-Triggered Depropargylation Enables Controllable Drug Activation in Vivo

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Bioorthogonal decaging reactions for con...

4064-06-6 Process route

(3aR,5R,5aS,8aS,8bR)-5-(Bromo-phenyl-methoxymethyl)-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran
126841-28-9

(3aR,5R,5aS,8aS,8bR)-5-(Bromo-phenyl-methoxymethyl)-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran

benzaldehyde
100-52-7

benzaldehyde

1,2:3,4-di-O-isopropylidene-α-D-galactopyranose
4064-06-6

1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Conditions
Conditions Yield
With water; Yield given;
 
acetone
67-64-1

acetone

D-raffinose
512-69-6

D-raffinose

2,3;4,5-di-O-isopropylidene-β-D-fructopyranose
20880-92-6

2,3;4,5-di-O-isopropylidene-β-D-fructopyranose

1,2;4,5-di-O-isopropylidene-β-D-(-)-fructopyranose
25018-67-1

1,2;4,5-di-O-isopropylidene-β-D-(-)-fructopyranose

1,2:3,4-di-O-isopropylidene-α-D-galactopyranose
4064-06-6

1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
Conditions Yield
iodine; for 72h; Title compound not separated from byproducts; Heating;
27%
37%
28%
4 % Chromat.
iodine; for 72h; Title compound not separated from byproducts; Heating;
27%
4%
28%
37 % Chromat.
iodine; for 72h; Title compound not separated from byproducts; Heating;
27 % Chromat.
37 % Chromat.
4 % Chromat.
28 % Chromat.

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    1,2:3,4-di-O-isopropylidene-6-iodo-D-galactopyranose

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4064-06-6 Downstream products

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